Counter-current centrifugal device and use

ABSTRACT

An apparatus which includes a housing defining a chamber therein, at least two rotatable plates in spaced, face-to-face relationship defining a channel therebetween; at least one inlet for feeding fluid material into the channel; a plurality of spaced outlets for removing the processed material, at least one of which is spaced radially from the center of rotation of the plates, and means for interrupting the laminar flow in said channel, preferably by means of a zig-zag configuration in at least a portion of the surface of said plates, more preferably adjacent the periphery. A counter-current flow pattern is provided by introducing a displacement fluid into the channel. Preferably, the plates are mounted on the same shaft and the inlet for material to be processed is through one plate adjacent to the shaft, and one outlet is through the other plate adjacent to the shaft. The apparatus can be used as a classifier, concentrator, or for washing materials of different density or the same density and different mass.

United States Patent [19 1 Timson [54] COUNTER-CURRENT CENTRIFUGAL DEVICE AND USE [75] Inventor: William J. Timson, Belmont, Mass.

[73] Assignee: Polaroid Corporation, Cambridge,

Mass.

[ 1 Notice: The portion of the term of this patent subsequent to Mar. 3, 1987, has been disclaimed.

[22] .Filed: Nov. 27, 1970 21 Appl. No.: 93,038

[52] US. Cl. ..209/211, 209/144, 241/251,

259/6, 259/105 [51] Int. Cl. ..-....B04b 5/12 {58] Field of Search ..209/21l, 144, 145,

209/148; 210/512; 55/17; 233/15; 241/188 A, 251, 255; 252/359 R, 359 A, 359 C, 360;

3,269,537 8/1966 Kaiser ..209/l44 3,334,869 8/1967 Mukai ..259/6 146,324 1/1874 Denmeacl ..24l/25l X 2,199,015 4/1940 Toensfeldt ..209/144 X 2,639,901 5/1953 Teale ..241/l88 A 2,665,061 1/1954 Steinacker et al ..233/l5 OUTLET OUTLET 2o CHANNEL 22 451 *May 8, 1973 3,089,595 5/1963 Kaiser ..209/l44 3,133,880 5/1964 Madanym 3,202,347 8/1965 Thurman ..233/l5 [57] ABSTRACT An apparatus which includes a housing defining a chamber therein, at least two rotatable plates in spaced, face-toface relationship defining a channel therebetween; at least one inlet for feeding fluid material into the channel; a plurality of spaced outlets for removing the processed material, at least one of which is spaced radially from the center of rotation of the plates, and means for interrupting the laminar flow in said channel, preferably by means of a zig-zag configuration in at least a portion of the surface of said plates, more preferably adjacent the periphery. A counter-current flow pattern is provided by introducing a displacement fluid into the channel. Preferably, the plates are mounted on the same shaft and the inlet for material to be processed is through one plate adjacent to the shaft, and one outlet is through the other plate adjacent to the shaft. The apparatus can be used as a classifier, concentrator, or for washing materials of different density or the same density and different mass.

15 Claims, 4 Drawing Figures INLET MATERIAL TO BE PROCESSED INLET FOR DISPLACEMENT FLUID Patented May 8, 1973 3,731,800

2 Sheets-Sheet 1 INLET MATERlAL OUTLET TO BE PROCESSED OUTLET INLET FOR DISPLACEMENT FLUID ZOCHANNEL 22 FIG.|

, l6 INLET MATERIAL T0 BE PROCESSED OUTLET 38 INLET FOR- 37 DISPLACEMENT OUTLET FLU'D INVENTOR.

WILLIAM J. TIMSON Mm MM and.

14; a RN EW 'IINLET FQRJ DISPLACEMENT FLUID Ptented May 8, 1973 3,731,800

2 Sheets-Sheet 2 INLET MATERlAL TO OUTLET BE PROCESSED OUTLET -|NLET FOR DISPLACEMENT FLUID CHANNEL INLET MATERIALTO Jae PROCESSED-V .OUTLETV BACKGROUND OF THE INVENTION This invention relates to an improved counter-current centrifugal exchange device and to the method of separating materials of different densities or materials of the same density and different mass.

U. S. Pat. No. 3,498,454 is directed to a particularly preferred counter-current centrifugal exchange device for separating materials of different densities or materials of the same density and different mass. The device disclosed therein includes a housing defining a changer therein, at least two rotatable plates in spaced, face-toface relationship defining a channel therebetween, means for introducing fluid material into the channel and outlets, preferably spaced radially from the center of rotation of the plates, preferably at the periphery of the plates or in the wall of the housing. In operation, a fluid containing, e.g., material of different particle size, is introduced between the rotating plates which set up a centrifugal force in the channel driving the particles toward the periphery of the plates. Simultaneously, a counter-current flow is established by the introduction of fluid into the housing from a point spaced apart from the center of rotation which serves to carry the smaller particles back towards the center of the plates, thus providing the desired separation of the different particle sizes.

However, when the rotatable plates employed are relatively flat, a radial laminar flow pattern is established in the channel wherein the material of relatively smaller density of mass moves toward the periphery of the plates substantially adjacent to the surfaces of the plates in a low velocity fluid area, thus reducing to some degree the efficiency of the system by, in effect, removing some of the relatively less dense material from the full effect of the counter-current flow.

A device has not been found which provides a more efficient separation operation.

SUMMARY OF THE INVENTION The novel apparatus of the present invention comprises a housing defining a chamber therein which contains at least a first and second rotatable plate defining a channel therein; means for introducing fluid material into said channel; means for removing processed material; means for providing a counter-current flow in said channel; and means for interrupting the radial laminar flow in said channeLPreferred means for interrupting said flow comprise plates defining a tortuous path therebetween.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a longitudinal section through the novel apparatus illustrating the general construction thereof;

FIG. 2 is a longitudinal section illustrating an alternative embodiment of the novel apparatus of the present invention;

FIG. 3 is a longitudinal section illustrating still another embodiment of the novel apparatus of the present invention; and

FIG. 4 is a longitudinal section illustrating still another alternative embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION The novel apparatus of the present invention comprises a housing defining a chamber which contains at least a first and second rotatable plate or disc mounted therein in face-to-face relationship and defining a tortuous channel therebetween. The plates are preferably mounted on shafts. Inlet means are provided for introducing the material to be processed into the chan- 0 nel. Outlets for removing processed material are provided with at least one outlet spaced radially from the center of rotation of the plates. Preferably, material to be processed is introduced into the space between the plates near the shaft, that is, near the center of rotation of the plates. An outlet for the processed material of lower density or mass is also preferably located in proximity to one of the shafts. Baffle means, or distribution means are optionally employed, to aid the distribution or the prevent a direct flow of the material to be processed through the housing from the inlet to the outlet without being processed by the centrifugal forces set up by the rotation of the plates.

Counter-current force is applied to the material in the housing by the introduction of a fluid from a point spaced apart from the center of rotation of the plates. An outlet for the material of greater density or mass is located spaced apart from the center of rotation of the plates since this material will be forced towards the periphery of the plates and toward the housing walls by the centrifugal force exerted by the rotating plates. The inlet for a displacement fluid or washing fluid to provide the counter-current flow is preferably located in one of the plates adjacent the periphery. In still another alternative embodiment, baffles are provided on the housing walls to prevent channeling, to provide uniform turbulent flow in the housing and to prevent rotation of the fluid. If desired, filtering means are employed in conjunction with the outlets or inlets to provide still further classification of materials.

In employing the novel apparatus of the present invention, the fluid material to be processed is introduced into the housing into the space or channel between the plates. The inlet, which is located close to, or preferably through a hollow shaft, i.e., at or near the center of rotation, introduces the material into a channel formed by the rotation of the plates where it is subject to the centrifugal and counter-current forces. Also in close proximity to a shaft is an outlet for the material of lower density or size. The channel is preferably baffled to prevent the direct passage of the material through the housing without undergoing the action of the centrifugal force and counter-current treatment in the channel between the plates.

If desired, the devices are operated in series or in various combinations, for example, with the exit stream from one device feeding into the inlet of another to provide any combination of separation, washing, or classification operations.

The action of the rotating plates sets up a centrifugal force which drives the materials of greater density or mass toward the periphery of the plates and the walls of the housing while the material of lesser density or mass move, as a result of the countencurrent flow pattern provided by the introduction of a fluid into the chamber from a point spaced apart from the center of rotation, toward the center of the plates, i.e., the center of rotation where the centrifugal force is minimal. The

less dense material or smaller particle size material, as stated above, is preferably drawn off from a point near the shaft or through the shaft, while the material of greater density is drawn off from an outlet in the plates adjacent to the periphery. Preferably, an inlet is located adjacent to the periphery of one of the plates to provide for the insertion of displacement or washing fluid into the housing, which provides counter-current action to drive the material of lesser density or mass towards the center of rotation.

By interrupting the radial laminar flow in the channel of the material to be separated, the material moving toward the periphery of the plates under the influence of the centrifugal force is thrown into more intimate contact with the counter-current action and away from proximity to the walls of the channels, i.e., the faces of the plates, whereby the counter-current flow will act upon the material of relatively less density or mass carrying it towards the center of rotation. The material of relatively large density or mass, of course, will be substantially unaffected by the counter-current action and will continue toward the periphery of the plates under the influence of centrifugal force.

It is preferred that the interruption in the radial laminar flow be accomplished by providing at least a portion of the channel with a tortuous path which will divert the material of less density or mass near the walls into the center of the higher velocity flow region of the laminar flow profile from the low velocity flow region, towards the center of channel under the influence of counter-currents thereby obtaining greater efficiency of the counter-current action.

The tortuous path is provided by modifying at least a portion of the plates, preferably adjacent the periphery, with baffles or undulations, i.e., successive raised and depressed areas which will direct the material of lesser density or mass away from its low fluid velocity path into more intimate contact with the higher velocity counter-current flow. More preferably, at least a portion of the plates contain a zig-zag configuration.

It is only necessary that a relatively small portion of the plates be modified in order to disrupt the radial laminar flow and obtain the increased efficiency. However, the greater the degree of modification, the greater the disruption or prevention the escape of the material of lesser density or mass along the plate walls in the laminar flow pattern and the resultant increase in efficiency in separation.

The degree of rotation of the plates is selected with regard to the speed with which the materials are to be separated and the composition of the material introduced into the apparatus. The plates may be rotated in the same or in opposite directions; preferably the rotation is in the same direction. In a particularly preferred embodiment, the plates are rotated at the same speed in the same direction. If the plates are rotating in the opposite direction, a differential in the rotational speed is necessary to provide the centrifugal force.

As stated above, the outlet for the material of greater density or mass is preferably located in the periphery of one or more of the plates or in the wall of the housing; that is, in the area of the greater concentration of material driven outward by the centrifugal force. In an alternative embodiment, a hollow or channeled plate is employed with ports located at varying spaced positions on the face of said plate whereby material of varying density or particle size fractions can be removed from the apparatus. In still another embodiment, a series of ports of different cross sections can be located in the periphery of the plate.

While the face of the plates is preferably flat, the plates or portions thereof may be parabolic in configuration.

ln employing plates with a series of ports on the face thereof for the removal of various fractions, sections of the face of the plates are preferably parabolic to pro vide a predetermined balance of flow rate to centrifugal force at various points along the face of the plate so that material ofa specific density or mass would stop its outward movement at a pre-selected point along the face of the plate and remain suspended at this particular point, thereby permitting the removal of this particular fraction through the aforementioned ports.

The spacing of the plates, i.e., the width of the channel, is not critical and can range from the size of the largest particle of material to be processed to a spacing many multiples of the particle size. The selection of the particular spacing is, therefore, determined by the material to be processed and the desired speed with which the separation or other procedure is accomplished. The length of the channel defined by the plates (radices of the plate) is not critical.

In one example, an apparatus of the present invention having a channel 2% inches long with a A inch zigzag configuration adjacent the periphery of the plates and a spacing between the plates of about 0.1 centimeter was able to separate particulate matter in a fluid to an accuracy of i 0.1 micron in diameter, where the particle size ranged from 0.4 to 5.0 microns in the material introduced into the channel.

Referring now to the drawings, FIG. 1 shows housing 10 having mounted therein plates 11 and 12 mounted on rotatable shafts 13 and 14; said plates being spaced apart and defining tortuous channel 20 therebetween by virtue of the zig-zag configuration 30 located adjacent the periphery of the plates 11 and 12. The material to be processed is introduced into the apparatus through conduit 15 and inlet 16 and distributed by baffle 27 into channel 20. The centrifugal and counter-current forces exerted on the material in channel 20 directs the material of greater density or mass away from the center of the plates and toward the outer walls of the housing, from which it is removed from the apparatus through outlet 21. Radial laminar flow in channel 20 is interrupted when the material to be processed passes zig-zag 30. Inlet 22 in the housing wall provides means for introducing a washing or displacement fluid into the housing to provide countercurrent forces and to also facilitate the removal of the higher density material through outlet 21. The lower density or mass material passes through conduit 18 in shaft 14 and is removed from the apparatus through outlet 19.

FIG. 2 illustrates an alternative embodiment showing housing 10 having mounted therein plates 11 and 12 mounted on rotatable shafts l3 and 14; said plates being spaced apart and defining tortuous channel 20 therebetween by virtue of the baffles 35 located adjacent the periphery of the plates 11 and 12. The material to be processed is introduced into the apparatus through conduit and inlet 16 and distributed by baffle 27 into channel 20. The centrifugal and counter-current forces exerted on the material in channel directs the material of greater density or mass away from the center of the plates and toward the periphery of the plates, from which it is removed from the apparatus through outlet 36 through conduit 37 and outlet 38. Radial laminar flow in channel 20 is interrupted when the material to be processed passes baffles 3S. Inlet 39 in shaft 13 provides means for introducing a washing or displacement fluid into the housing through conduit 41 and inlet 42 to provide counter-current force and to also facilitate the removal of the higher density material through outlet 36. The lower density or mass material passes through conduit 18 in shaft 14 and is removed. from the apparatus through outlet 19.

FIG. 3 illustrates an apparatus similar in construction to that shown in FIG. 1 except that plates 11 and 12 are mounted on a single shaft 14. The material to be processed enters the channel through ports 50 and lower density material exits into conduit 18 through ports 51 and shaft 14.

FIG. 4 is still another alternative embodiment of the present invention similar in construction and operation to the apparatus shown in FIG. 2 except that the inlet for displacement fluid 39 is located in shaft 14 and outlet 38 is located in shaft 13.

In the above indicated figures, means for rotating the shafts comprise electric motors M.

The novel apparatus of the present invention may be employed for a variety of processing applications. As described above, it may be employed for separating materials of different densities or masses. The material to be processed is introduced into the channel between the plates at a point near the center of the plate and a first outlet means is provided near the center of the plate and a first outlet means is provided near the center of the plate or through the shaft for the material of lesser density or mass and a second outlet spaced away from the center of rotation of the plates, preferably in the periphery of the plates or in the wall of the housing, provides for the removal of material of greater density or mass which moves away from the center of rotation as a result of the centrifugal action set up by the rotation of the plates. Counter-current action is provided by the displacement fluid, such as wash water, which is introduced into the housing from a point in the wall of the housing on the periphery of the plates.

In alternative embodiments, various combinations of open and closed inlets and outlets can be employed to provide a variety of effects. A gross separation of materials can be achieved by closing the inlet for the displacement fluid and also closing the outlet spaced apart from the center of rotation to provide removal of smaller particles and retension of the larger particles in the apparatus.

The apparatus is also employed as a concentrator wherein only the liquid is removed. For example, the novel apparatus of the present invention has especial utility in separating insoluble salt in fluids by removal of the liquid alone while the salts are concentrated within the housing. Material is fed at a relatively slow rate so that all the particulate material will move away from the outlet in the shaft. When the concentration of the particulate salt reaches a point wherein the efficiency of the apparatus is substantially decreased, a port in the wall of the housing may be opened to bleed-off the relatively high concentration of the particulate matter.

In still another embodiment, the novel apparatus may be employed as an emulsifier by the introduction of material to be emulsified into the channel and then closing all of the inlet and outlet ports in the apparatus. The transverse shear set up by the rotating plates would provide the emulsification action. In this matter, the novel apparatus can also be employed as a colloid mill. As an illustrative example, the rotation of one plate at 5,000 rpm and the second plate at 25,000 rpm will provide a colloid having a particle of less than micron size.

The novel apparatus of the present invention possess great utility for a broad spectrum of counter-current mass transfer operations involving (a) solid-liquid systems, (b) liquid-liquid systems and (c) gas-liquid systems and combinations thereof.

The apparatus can process materials of different densities, or the materials of the same density and different masses. Unlike prior art devices, the apparatus processes sticky and hard to handle materials with ease since there are no small passages or perforations in bands which can plug or otherwise become fouled. The combined centrifugal and counter-current action provides a cleaning operation during the processing.

The novel apparatus of the present invention is particularly useful in processing silver-halide-gelatin photographic emulsions. The apparatus is employed to perform a variety of processing operations on the emulsion. For example, efficient washing of flocculated emulsions may be achieved; emulsion grains may be classified into desired distribution ranges; silver halide grains may be concentrated into a smaller volume of fluid and the continuous phase of an emulsion may be displaced by a second continuous phase.

As illustrative of the novel process of the present invention, the classification of a photographic emulsion into the desired particle size range is described. The emulsion to be of is introduced into the channel between the rotating plates. The centrifugal force drives the larger, coarser particle fraction of the emulsion toward the outer periphery of the plate where it leaves the apparatus by an appropriate exit passage located near the periphery of the plate either in the wall of the housing or in the plate itself. The removal of the coarser particle size material isfacilitated by the introduction of distilled water as a wash liquid into the area of the greater concentration of the coarse material. The finer particle size emulsion material is displaced toward the center 0d the rotating discs by the countercurrent flow and is removed from the rotation.

The following non-limiting example illustrates the employment of the novel apparatus of the present invention to separate a material according to particle size.

EXAMPLE Employing an apparatus similar to that set forth in FIG. 2, a conventional photographic silver halide gelatin emulsion, having a particle size distribution from about 0.4 to 5.0 microns (as determined by Histogram), was introduced into the channel between two plates of inch OD. The length of the baffle portion of the channel was one-half inch with the distance between the baffles on opposite plates one thirtysecond inch. The two plates were rotating in the same direction at a speed of about 2,400 rpm, The the material passing through the small particle outlet 18 in plate 12 was less than 1 micron in diameter. Particles having a diameter of one to two microns were removed continuously through outlet'36 in plate 1.1. Materials greater than 2 microns in diameter remained in the apparatus and were removed from time to time to prevent excessive build-up of the larger particle size in the apparatus.

The novel apparatus of the present invention is also of particular value in processing photographic silver halide-gelatin emulsions, in that the present invention provides a method by which unflocculated grains can be washed. In the past, it was necessary to carry out the washing step for the removal of soluble salts, such as potassium nitrate, which are formed during the emulsion preparation, by treating a flocculated emulsion or noodling the emulsion. By means of the present invention, however, the individual grains can now be washed, thereby providing greater efficiency of salt removal, and emulsions with greater uniformity or particle size which heretofore has not been obtainable on a commercial scale.

By employing the novel apparatus of the present invention, it is also possible to prepare a silver halidegelatin emulsion and then replace the gelatin phase of the emulsion with another suspending polymer, such as polyvinyl alcohol. In such an exchange operation, the silver halide gelatin emulsion would be introduced into the channel between the rotating plates while at the same time polyvinyl alcohol would be introduced into the apparatus through an inlet in the housing. The centrifugal force and counter-current forces set up would be such that the gelatin would move to the center of the plates and be removed through the outlet in the shaft while the silver halide particulate matter would be driven toward the periphery of the rotating plates. Outlets for the particulate matter would be closed thereby retaining it in the housing during the exchange of the gelatin for the polyvinyl alcohol.

What is claimed is:

1. An apparatus which comprises:

a housing defining a chamber therein;

at least a first and second plate in opposed spaced relationship;

said plates defining a channel therebetween said channel being disposed in a radial direction;

means for rotating said plates;

means for introducing a first fluid material into said channel;

a plurality of spaced outlet means for removing said fluid material, at least one of said outlet means being spaced radially from one other of said outlet means;

means for interrupting radial laminar flow of said interruption means com rises baffles on said plates.

4. T e apparatus as efined in claim 1 wherein said first and second plates are mounted on first and second rotatable shafts respectively.

5. The apparatus as defined in claim 1 wherein said means for rotating said plates comprise a single shaft.

6. The apparatus as defined in claim 4 wherein said means for introducing said first fluid material and at least one of said outlet means for removing material are associated with said rotatable shafts.

7. The apparatus as defined in claim 1 which includes baffle means associated with said means for introducing said first fluid material to provide distribution of said material in said channel.

8. The apparatus as defined in claim 1 wherein at least one of said outlet means is located in the periphery of one of said plates.

9. The apparatus as defined in claim 8 wherein said second means for introducing a fluid material is spaced radially from the center of rotation of said plates.

10. The apparatus as defined in claim 9 wherein said second means for introducing a fluid material is spaced radially from said first means for introducing a fluid material.

11. The apparatus as defined in claim 10 wherein said first means for introducing a fluid material is associated with said first plate and said second means for introducing a fluid material is associated with said second plate.

12. The process for the separation of materials into fractions with respect to density or mass which comprise the steps of introducing a first fluid material containing elements of differing density or mass into a channel intermediate a first and second plate in faceto-face spaced relationship, rotating said plates to provide a centrifugal force to said material in said channel, introducing a second fluid into said channel to provide a counter-current flow with respect to said centrifugal force providing a radial laminar flow of fluid in said channel, interrupting the radial laminar flow in said channel, thereby separating said elements as a function of their density of mass, and collecting at least one fraction of said first material so separated.

13. The process as defined in claim 12 wherein a lower density or mass fraction is collected adjacent the center of rotation of said plates and a higher density or mass fraction is collected at a location spaced radially from said center of rotation.

14. The process as defined in claim 12 wherein said first material is photographic silver halide dispersed in a polymeric matrix.

15. The process as defined in claim 13 wherein the fluid for providing said counter-current flow is water. 

1. An apparatus which comprises: a housing defining a chamber therein; at least a first and second plate in opposed spaced relationship; said plates defining a channel therebetween said channel being disposed in a radial direction; means for rotating said plates; means for introducing a first fluid material into said channel; a plurality of spaced outlet means for removing said fluid material, at least one of said outlet means being spaced radially from one other of said outlet means; means for interrupting radial laminar flow of said fluid material in said channel; and a second means for introducing fluid material.
 2. The apparatus as defined in claim 1 wherein said interruption means comprises a zig-zag configuration in said plates.
 3. The apparatus as defined in claim 1 wherein said interruption means comprises baffles on said plates.
 4. The apparatus as defined in claim 1 wherein said first and second plates are mounted on first and second rotatable shafts respectively.
 5. The apparatus as defined in claim 1 wherein said means for rotating said plates comprise a single shaft.
 6. The apparatus as defined in claim 4 wherein said means for introducing said first fluid material and at least one of said outlet means for removing material are associated with said rotatable shafts.
 7. The apparatus as defined in claim 1 which includes baffle means associated with said means for introducing said first fluid material to provide distribution of said material in said channel.
 8. The apparatus as defined in claim 1 wherein at least one of said outlet means is located in the periphery of one of said plates.
 9. The apparatus as defined in claim 8 wherein said second means for introducing a fluid material is spaced radially from the center of rotation of said plates.
 10. The apparatus as defined in claim 9 wherein said second means for introducing a fluid material is spaced radially from said first means for introducing a fluid material.
 11. The apparatus as defined in claim 10 wherein said first means for introducing a fluid material is associated with said first plate and said second means for introducing a fluid material is associated with said second plate.
 12. The process for the separation of materials into fractions with respect to density or mass which comprise the steps of introducing a first fluid material containing elements of differing density or mass into a channel intermediate a first and second plate in face-to-face spaced relationship, rotating said plates to provide a centrifugal force to said material in said channel, introducing a second fluid into said channel to provide a counter-current flow with respect to said centrifugal force providing a radial laminar flow of fluid in said channel, interrupting the radial laminar flow in said channel, thereby separating said elements as a function of their density of mass, and collecting at least one fraction of said first material so separated.
 13. The process as defined in claim 12 wherein a lower density or mass fraction is collected adjacent the center of rotation of said plates and a higher density or mass fraction is collected at a location spaced radially from said center of rotation.
 14. The process as defined in claim 12 wherein said first material is photographic silver halide dispersed in a polymeric matrix.
 15. The process as defined in claim 13 wherein the fluid for providing said counter-current flow is water. 